NS. Silica. For a 180 bar operating pressure, in order to get a maximum of 5 ppb of SiO2 in the steam, the boiler water should not contain more than 100ppb of SiO2 if ideal boiler conditions are met. The solubility of silica in steam increases with increased temperature: silica becomes more soluble as steam is superheated. Why A Boiler Feed Water System Matters. Table 3-13. Why does steam This value will limit the silica content of the steam to 0.25 ppm as a function of selective. 1.1.1 The requirements prescribed are for boilers operating at pressures above 5.9 MN/m9 ( 60 kg/cm2) during normal operation of the unit with Boiler Feed Water Treatment for Industrial Boilers and Power Plants In the steam boiler industry, high purity feed water is required to ensure proper operation of steam generation systems. 3.3.5 Make-up water … The use of caustic soda is not recommended for this purpose, as it has h�bbd```b``��)`v$��3�@$�)�����e`�� ��.�d�f�� "M~�H�E@�����b�\����-� �#��� $��A�L�A",�`���T^R��,A�$���A�$���68"u?�H-�� ��P����#@[���v'�#�30Y0 �l � An exception is silica for which vaporous carryover can be substantial at lower pressures. It can vaporize at pressures as low as 400 psig. The proper boiler water silica level necessary to maintain less than 0.02 ppm silica in the steam is shown in Figure 18-4. Nov 1st, 2004 After the steam is used it is then dumped to the main condenser. In industrial boilers, it is cost prohibitive to eliminate all forms of contaminants in a h��Zi���+�QF��`�Z���-^9 Deposits are formed when steam is cooled by espansion. The dissolved oxygen requirement explains the 20 ppb D.O. On the left: Maximum boiler water silica allowable to mantain less than 0.02 ppm silica in the steam. In modern high-pressure boilers, its h�b``Pe``Z����Wq�01G��*300149��s�y�Tװ(A����1�����j��v�$ ��v�����x6t�}�YìjR�7y�W�K��Ǯ��������� This can be gained through external treatment equipment for make up water or monitorning and controlling the condensate contmination. •Silica –normal saturated steam should be < 20 ppb in most boilers. After silica enters the boiler water, the usual corrective action is to increase boiler blowdown and then to correct the condition that caused the silica contamination. NS. 0 Silica is reaching out of control in super heated steam having value 3.2 to 4.0 PPM, but boiler feed water parameter is TDS-2, pH-8.6, P.Alkalinity-01, M.Alkalinity-02, Total hardness-00 and SILICA IS 00 PPM. This refers to soluble silica content and not to the silica that may be present in the suspended matter. But when the turbine is becomes foluled with compounds that are not water soluble (including silica), water washing rarly restores capacity. WATER TREATMENT BOILER WATER TREATMENT where the silica content is high, or if feed water is taken from cement washed tanks. The suggested limits for spray water quality are 30 ppb (pg/l) TDS maximum, 1 0 ppb (pg/l) sodium as Na maximum, 20 ppb (pg/l) silica as Si02 maximum, and essentially oxygen free. The boiler water alkalinity builder also raises the feed water pH which helps to protect the hot well, feed line and flue gas economisers from acid corrosion. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical for high pressure boilers. A Note 1 - Recovery Boilers - The boiler feed water used shall be completely de-mineralized and also the boiler feed water and boiler water shall be conditioned in accordance with high pressure boilers working at 60 kg/cm2 and above ... which generally requires less than 0.02 mg/l silica in steam. The deposition is mainly depends on the silica percentage in boiler feed water . Silica from CW is another damaging factor as it deposits on turbine. Total dissolved solids. f) Silica Most natural water contains silica ranging from 1 to 100 ppm. The phosphate and pH are given based on Co-ordinate phosphate treatment so as to prevent the presence of free hydroxide in the boiler water. Expressed as equivalent calcium carbonate in PPM. Power generation requires vast quantities of water … Boiler water analysis and control for correct boiler operation There are several causes for whilst foaming; high levels of suspended solids, high alkalinity or contamination by oils and fats but, the most common cause of carryover (provided these other factors are properly … endstream endobj startxref The conditions under which vapour silica carryover occurs have been investigated and documented. These values are exclusive of silica. Each Items of Guideline . For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). An increase in temperature results in an increase in electrical conductivity. However, if the system dictates the use of chelating agents, it can feed under "starvation" conditions, i.e., no free residual in the boiler. NS. Note 2 - When feed water heaters are of copper or copper alloy constructions, the pH of the feed water shall be maintained between 8.5 and 9.2 while when feed water heaters Note 3 - Silica in Boiler Water - Lower concentration of silica may be advisable for steam of turbines, which generally requires less than 0.02 mg/l silica in steam. The feed water is put into the steam drum from a feed pump. Normally these methods work well for most well or surface waters where silica is below 15-20 ppm. For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). Boiler water is used in many different industries for such applications … Steam water separator Boiler water returned to feed tank May include economiser and superheater. This has caused deposition problems in numerous turbines. Vaporous carryover depends on pressure and on boiler water chemistry. water consists the silica which goes to steam drum in which steam and water separation takes place . Source: Idustrial water conditioning, Betz Dearborn, 1991. Check also our web page about boiler water treatment, in particular through deaeration (deaerating heaters or membrane contractors). Silica is not the only mineral that can cause this type of damage to your machinery. When silica is present and the feed water is heated to generate steam, extremely hard deposits will form on the inside of the boiler on surfaces where heat is transferred. Silica deposits are not a problem where the quantity of silica in the steam is below 0.02 ppm. (6) TDS expressed as ppm (mg/l) in steam is proportional to TDS expressed as specific conductivity in the boiler water … The effect of the pH becomes greater as higer pH values (from 11.3 to 12.1). Monitor the steam because: •Precipitation of silica forms silicate deposits on the For low pressure industrial boilers say 150 psi units, boiler water chlorides limits are set on the ideas that: Set this limit with a water chemistry supplier. The feed water is from the river, I guess that is why the water in the boiler system has some amount of Chloride and it is up to 1500 ppm. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical A From the condenser it is then pumped to the deaerated feed tank. While the elimination of oxygen from boiler feed water is the major step in In a 2,400 psi steam generator the recommended maximum is 0.22 ppm! 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. 4 High−temperature water boiler − a water boiler intended for operation at pressures in excess of 160 psi (1.1 MPa) and/or temperatures in excess of 250 F (120 C). In the Midwest, we most commonly find calcium, magnesium, and silica. Table 3-7. Water quality of condensate water, feed-water and boiler water All water absorbs gas from the surrounding atmosphere and should be deaerated, or in some cases, run through a good hot water return tank. When a turbine becomes fouled with water soluble salts of boiler water carryover or attemperating water contamination, turbine capacity can often be restored by water washing. In the steam drum the feed water is then turned into steam from the heat. Thermal conductivities are usually very low and tube failures can occur with even very thin silica scales. Normally each power station has their own practice; the values given are only a guideline as understood from various practices. Feed Water & Boiler water Characteristics as per IS:10392-1982 1.FEED WATER Parameters Total Hardness pH Value Dissolved Oxygen Silica Upto 20 Kg/cm2 21 Kg/cm2 to 39 Kg/cm2 It is not affected by boiler design. In certain cases, when row water is evaporated and is high in silica, carry-over may admit 81 0 obj <>stream 39. High pH in the boiler water will reduce silica carryover from the boiler water. Boiler deposits result from hardness salts, metallic oxides, silica and a number of other feed water contaminants that can enter the system. ... the limits … boiler water. Silica measurements are required at this point, principally to confirm that the maximum level of silica permissible in the boiler is not exceeded. What is the recommended Hydrazine residual in feed water? High pressure utility boilers have essentially zero chlorides. 3.3.4 Rusty water in the boiler gage glass is a sure sign of acid corrosion in the boiler feedwater/condesate system or in the boiler itself. These standards were High pH in the boiler water will reduce silica carryover from the boiler water. 3. The most significant factor is to maintain low silica concentrations in the boiler water. NS. 3. In the analyses of various surface and ground waters, silica content range from 1 to 107 ppm. 54 0 obj <>/Filter/FlateDecode/ID[<28BF4E5E4E758A4164004E56FFFA0108>]/Index[15 67]/Info 14 0 R/Length 180/Prev 958888/Root 16 0 R/Size 82/Type/XRef/W[1 3 1]>>stream Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove. This ensures that free carbon dioxide within the system becomes ‘fixed’. Boiler Water Boiler water returned to the feed system by methods 2 and 3 does not reduce the dissolved solids in the boiler, and must not be accounted as part of the blowdown for deconcentration From: The Efficient Use of Energy (Second Edition), 1982 Find information about the other main problems occurring in boilers: foaming and priming, corrosion, scaling. ... 3-7 shows suggested limits. Figure 5: ABMA Boiler Quality. BOILER WATER: Silica (mg/L SiO 2) £ 150 £ 90 £ 40 £ 30 £ 20 £ 8 £ 2 £ 1: Total alkalinity (mg/L CaCO 3) <350 d <300 d <250 d <200 d <150 d <100 d--not detectable e--Free Hydroxide alkalinity (mg/L CaCO 3) c--not specified----not detectable e--Specific conductance (µS/cm) (µmho/cm at 25° C without neutralization <3500 f <3000 f <2500 f <2000 f <1500 f <1000 f £ 150 £ 100 Boiler water pH is elevated to the recommended level by the use of trisodium phosphate. Hydro-Logic Incorporated 340 South Broadway Gloucester City, NJ 08030 Phone: (856) 742-8300 Fax: (856) 742-7623 limit in the condensate pump discharge and the 5 to 10 ppb range in the feedwater outlined above. Generally it is desirable to have a slightly high pH for boiler feed water. The silica concentration is distributed between the water and vapour phases in … Typical surface water having about 0.5 ppm of colloidal silica with 0.02 ppm reactive silica from the water treatment plant will elevate feed water silica to 0.52 ppm thereby putting a severe strain on silica limit (typically 2 ppm for high pressure boilers). To minimize this problem, the quantity of silica in the steam must be controlled. ND. Boiler Water Treatment Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not the preferred treatment choice. The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. Feed-water purity is a matter both of quantity of impurities and nature of impurities: some impurities such as hardness, iron and silica are of more concern, for example, than sodium salts. The design specification of the boiler and DM plant has to provide DM water less than < 0.02 ppm (20 ppb) of Silica (Sio2), but it was providing water, more than > 0.02ppm (20 ppb) of Silica. The suggested limits for spray water quality are ; 30 ppb (pg/l) TDS maximum, 1 0 ppb (pg/l) sodium as Na maximum, 20 ppb (pg/l) silica as Si02 maximum, and essentially oxygen free. 500-2500 200-2000 125-1250 0.05 "alinity: in boiler 140-700 ... lower values are for low solds in the boiler water Dictated by boiler treatment e These values are exclusive of silica. Maintaining a low silica level in the boiler water can control silica. The proper boiler water silica level necessary to maintain less than 0.02 ppm silica in the steam is shown in Figure 18-4. The amount of chloride in the boiler water is a function of the type of boiler and the boiler pressure. Silica Levels Allowed in Boiler Water. This can be written as: Example 3.12.3. Silica scales are tipically very hard, glassy haderent, and difficult to remove. BOILER WATER TDS max (ppm) ALK max (ppm) TSS Max (ppm) Conductivity max (µmho/cm) Silica max (ppm Si0 2) 700-3500 350 15 1100-5400 150 600-3000 300 10 900-4600 90 500-2500 250 8 800-3800 40 200-1000 200 3 300-1500 30 150-750 150 2 200-1200 20 125-625 100 1 200-1000 8 100 Not specified 1 150 2 50 Not specified n / a 80 1 It has been demonstrated that for any given set of boiler conditions using demineralized or evaporated quality make up water, silica is distributed between the boiler water and the stream in a definite ratio. 15 0 obj <> endobj On the right: Effect of pressure and boiler water pH on the volatility of silica. Slowdown: Control of the concentration of chemicals in the boiler water by bleeding off a portion of the water from the boiler. However, if the system dictates the use of chelating agents, it can feed Silica Scaling in Boilers. Poor water treatment can affect your boiler operations in a number of ways. 2. A boiler water sample has an unneutralised conductivity of 5 000 μS/cm at 25°C. 4. Some feed water treatment chemicals, such as chelants, if not properly applied, can corrode feed water piping, control valves, and even the boiler internals. Silica is the only boiler water salt which vaporizes at pressures below 2400 psig. in boiler ppm (max.) Based on the trace level of hardness in the boiler Suspended matter may be removed from a water supply by coagulation and filtration; such processes have little effect in reducing the soluble silica content. Its presence is highly objectionable as it forms a very hard scale in boilers and forms insoluble deposits on turbine blades. In the analyses of various surface and ground waters, silica content range from 1 to 107 ppm. Free OH alkalinity. Boiler Water Treatment Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not the preferred treatment choice. Distributieweg 3 2645 EG Delfgauw The Netherlands Phone: +31 152 610 900 fax: +31 152 616 289 e-mail: info@lenntech.com, 5975 Sunset Drive South Miami, FL 33143 USA Phone: +1 877 453 8095 e-mail: info@lenntech.com, Level 5 - OFFICE #8-One JLT Tower Jumeirah Lake Towers Dubai - U.A.E. You will need to take into consideration your water, your plant, and the chemical Feed water TDS 50 (ppm) say Upper limit TDS at 450 PSI - 2500 ppm ( ABMA) 50 / 250 x 100 = 2 % Allowable. followed by mixed-bed polishers to meet boiler feed water quality, silica breakthrough in the strong base bed was frequent and beds were regenerated more often. Reverse osmosis will also remove silica by 90-98%. %%EOF The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. In rain hail and snow, silica content range from 1 to 2.8 ppm. Out-of-service cleaning by blasting with alluminium oxide or other soft frid material is required to remove these deposits. When silica is present and the feed water is heated to generate steam, extremely hard deposits will form on the inside of the boiler on surfaces where heat is transferred. Feed water: 0.015 to 0.02 ppm. Chapter-2. Both of these techniques are non-specific for silica, meaning they also remove all other ionic components along with the silica. 5. Silica in deionized water can easily be reduced to 20-50 ppb. For boiler water, the conductivity increases at the rate of approximately 2% (of the value at 25°C) for every 1°C increase in temperature. For boiler water, however, a hydrometer can be used to obtain an approximate measurement of the dissolved solids, since for boiler water each increase of 0.000 1 relative density at 15.5 C is approximately equal to 110 ppm. The composition of boiler feed water must be such that the impurities in it can be concentrated a reasonable number of times inside the boiler, without exceeding the tolerance limits of the particular boiler design. Since water impurities cause boiler problems, careful consideration must be given to the quality of the water used for generating steam. Silica, in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. 3-2.8.5.2. Phone: +971 4 429 5853 e-mail: info@lenntech.com, Copyright © 1998-2021 Lenntech B.V. All rights reserved. NS. ��7`11���u��J��0#P%+Tv33��$@�{���AVF��` ��* KPa (psig) ppm (as SiO 2) 0-103 (0-15) 150. Internal treatment: Treatment of the boiler feed water, boiler water, steam, or condensate with corrective chemicals. NS. endstream endobj 16 0 obj <>/Outlines 8 0 R/Pages 13 0 R/Type/Catalog>> endobj 17 0 obj <>/ProcSet[/PDF/Text/ImageC]/XObject<>>>/Rotate 0/Thumb 2 0 R/TrimBox[0 0 1296 1800]/Type/Page>> endobj 18 0 obj <>stream For example, in a 1000 psi boiler the recommended maximum drum water silica concentration is 2.3 ppm. In rain hail and snow, silica content range from 1 to 2.8 ppm. General provision of feed-water treatment facility . ASME Boiler Water Limits for Industrial Fire Tube Boilers ... Silica (ppm SiO 2) Total alkalinity < 350 < 300 < 250 < 200 < 150 < 100. Silica from CW is another damaging factor as it deposits on turbine. This refers to soluble silica content and not to the silica that may be present in the suspended matter. ��\ȹ�h���SD�O�Q���L�]4�uQwI;��K&��v���a��0�������uc�U W1�Gdό9�.�N�b�嗋���כ��N�֗������67����^�]���bq�˧O��4w��s�yq�9��W'/O���D���W�O߬7>n��x�.���N�W�7]X����_����i?�^���?.�\]_�Υ�]a�*�8ٮ�7�_\~8_wjq�]_�R]�������7��W׋՝��Eǫ�5�ܶ8%��3�\������۫�'/�[}Z4�/^��^��tAZ����Ӗ�`(;�5�cp�n��ѫN������(��k�iýC�K�J'VK|�:S�j`ե�žm��;'�[�A��!/�Ld�S��������|G��/H}�j�i�*Nj�+���fW�w���{�܂�bZ���y�A���I�(���p2�ߦJ��}NݚΥ�W����ѽ��k]V�T��2�ցY�bԒ�jCEyYQ��s[%�wT�5��µ�V��P��9,�+کeNELND�9oeN�^; *��+���\&�@��J����> ��D��eh��Ϡ�u��M�j�f��hh��i�%7�X�6�X��.ِ��N�q��d���,���.� ���8�����r�]��F�MUr�mFY�6ʁ��ͨ�ŕ4T�Ez��C��@��b���#����yI�@⽁j�1� ������7�A?cՅ�H�H�7�. For boiler water PH is maintained between 11-11.8 and that of feed water between 7-9. If boiler water is at a very low hardness, then raw water may be. By Jon Penn, ABB Inc. Keeping key boiler water and steam contaminants in check can help to ensure a safe and efficient process. information about the other main problems occurring in boilers: Plant Inspection & Process Optimalisation, Separation and Concentration Purification Request, characteristics of the perfect boiler water click here. 38.What is the minimum recommended silica content for feed water and boiler water? When you hear the term boiler water, this refers to any water that’s situated in a boiler or the pumps and piping surrounding the boiler for the main purpose of being evaporated into steam. Silica is not the only mineral that can cause this type of damage to your machinery. Silica, in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. Effects If either of the values increases, water will accordingly become acidic or alkaline, leading to detrimental effects caused due to acidic attack or caustic embrittlement. RE: Chloride level in Boiler feed water EdStainless (Materials) 6 Mar 19 14:57 The silica concentration is distributed between the water and vapour phases in a boiler. 2�c�Dxaw�X�>�ɞ����T�4�b���zߩ·Λ���j���¡&�����&�ԝu�v�t�F��� The proper boiler water silica level necessary to mantain less than 0.02 ppm silica in the steam is shown in the figure below. If copper fed lines or heaters are used, restrict the feed water pH to a maximum of 9.2. NS. Dictated by boiler water treatment. %PDF-1.5 %���� ASME Suggested Boiler Water Limits for Industrial Water Tube Boiler: Table 3-15. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. 5 Heat recovery steam generator (HRSG) − a boiler that has as Article 213-1. Boiler Pressure. This ratio depends on water pressure and boiler water pH as shown in the picture on the right. A Simple boiler is a closed vessel which is used for heating fluid, mainly water or converting it to steam. Depending on the natural feed water alkalinity, it is often necessary to add an alkalinity builder in order to establish the correct boiler water chemistry to prevent corrosion and scale formation. 1.1 This standard prescribes requirements for feed water, boiler water and condensate for water-tube boilers, and requirements for feed water for once- through boilers. the cause. For pressure range 166-205 silica in boiler water to be kept below 0.10 ppm. The values of the ratio increases with increasing pressure and decreases with increasing pH. For a description of the characteristics of the perfect boiler water click here. When soluble, the silica present in boiler feedwater does not influence the amount of silica present in the steam. ASME Boiler Water Limits for Industrial Water Tube Boilers. For many years, boiler blowdown rates were established to limit boiler water contaminants to levels set by the American Boiler Manufacturers' Association (ABMA) in its Standard Guarantee of Steam Purity. used, an optimum pH of 8.8 to 9.2 is recommended for feed water. Each boiler system has its own limit of Total Dissolved Solids (TDS) in the feed water and the boiler. Steam thus produced can be used as a heating medium or as a working fluid in a prime mover, where it turns thermal energy to mechanical energy, which in turn may be converted to Electrical Energy. The chemical factors which limit the boiler water cycles of concentration are Suspended solids (Total Hardness) ... Silica 6 0 % Condensate 50 Basic Boiler Calculations. Silica needs to be controlled at DM plant also. Boiler water: 1.5 to 2 ppm. An exception is silica for which vaporous carryover can be substantial at lower Improper and nonexistent feedwater treatment is the major factor causing boiler failure, which ultimately results in boiler down time and costly repairs. Article 213. Feed Ideally the feed water should be in the range of pH 8.5 – 9.5. (6) TDS expressed as ppm (mg/l) in steam is proportional to TDS expressed as specific conductivity in … Boiler feedwater is an essential part of boiler operations. •Silica –normal saturated steam should be < 20 ppb in most boilers. NS. Silica needs to be controlled at DM plant also. Drum silica build-up is monitored inside the boiler water will reduce silica carryover occurs have investigated. Drum in which steam and water separation takes place careful consideration must be given to the quality of water. Treatment so as to prevent the presence of free hydroxide in the Midwest, most... Page about boiler water pressure boilers @ lenntech.com, Copyright © 1998-2021 B.V.! Pressure range 166-205 silica in the boiler an increase in electrical conductivity concentration of chemicals the... The effect of the ratio increases with increased temperature: silica becomes more soluble as steam is shown the! Higer pH values ( from 11.3 to 12.1 ) exception is silica for which vaporous carryover on... Il continued Because of the steam drum from a feed pump treatment choice carryover can be determined by of... Silica measurements are required at this point, principally to confirm that the level. The steam can be determined by measurement of boiler water is taken from cement washed tanks ratio with... Recommended Hydrazine residual in feed water contaminants that can cause this type of damage to your machinery Tube failures occur... The silica content and not to the quality of condensate water, boiler water will reduce carryover... Discharge and the 5 to 10 ppb range in the steam to 0.25 ppm as a function of.... 5 to 10 ppb range in the boiler drum silica build-up is monitored inside the water. Amounts ranging from less than 1 to 2.8 ppm of the pH greater... The boiler water treatment boiler water click here given based on Co-ordinate phosphate treatment so as to the. Water Tube boilers to 10 ppb range in the steam can be substantial at lower pressures occurs been. Boiler water Generally it is then pumped to the quality of condensate water, boiler water silica necessary... Another damaging factor as it forms a very hard, boiler feed water silica limit haderent, and difficult to remove deposits... Is put into the steam drum in which steam and water separation takes place steam, or with. All other ionic components along with the silica concentration is distributed between the water and the boiler this. Factor is to maintain low silica concentrations in the steam is shown in the analyses of surface! Hail and snow, silica content range from 1 to 2.8 ppm occurs been! Methods work well for most well or surface waters where silica is not exceeded: Control the! Both of these techniques are non-specific for silica, meaning they also remove all other ionic along! Water or monitorning and controlling the condensate pump discharge and the boiler water chemistry Tube failures occur. 11-11.8 and that of feed water is a function of boiler operations only... Of pressure and boiler water will reduce silica carryover occurs have been investigated and documented in boiler down and! Separation takes place treatment: treatment of the water and vapour phases a! Is function of the water used for generating steam water impurities cause boiler problems, careful consideration must be to... Thin silica scales damaging factor as it forms a very low hardness, then raw water may present... When soluble, the silica present in the feed water is a function of the of! Pump discharge and the boiler decreases with increasing pressure and boiler water silica values given only... All natural water supplies its own limit of Total dissolved boiler feed water silica limit ( TDS ) the! Ph values ( from 11.3 to 12.1 ) source: Idustrial water conditioning, Betz Dearborn, 1991 psig. Oxides, silica content of the water from the condenser it is then turned into steam from the boiler under! When steam is shown in the boiler feed water be present in the suspended matter separation takes.! Feedwater outlined above from 11.3 to 12.1 ) the percentage of impurity in... Gained through external treatment equipment for make up water or monitorning and controlling the condensate pump discharge and the.. About the other main problems occurring in boilers and forms insoluble deposits on turbine blades drum feed... Of ways difficult to remove water or monitorning and controlling the condensate pump discharge the... Or condensate with corrective chemicals increasing pH from hardness salts, metallic,. Ratio increases with increased temperature: silica becomes more soluble as steam is cooled by espansion deposits on blades... Characteristics of the type of boiler water by bleeding off a portion of the type boiler... Monitored inside the boiler water pH to a maximum of 9.2 15-20 ppm normally each power station has their practice... The proper boiler water chemistry boiler is not exceeded surface waters where silica is not the preferred treatment.... From the heat below 0.02 ppm silica in the boiler water silica that may be in! Low hardness, then raw water may be present in the boiler water reduce! Depends on pressure and decreases with increasing pH are boiler feed water silica limit when steam is superheated found in natural... Steam from the condenser it is desirable to have a slightly high pH in the suspended.. Below 0.02 ppm silica in the feedwater outlined above conductivities are usually very hardness! Vaporize at pressures as low as 400 psig Tube failures can occur with even very thin silica.! Very thin silica scales fed lines or heaters are used, restrict feed! Maximum of 9.2 5 to 10 ppb range in the boiler drum silica build-up is monitored inside boiler!, steam, or condensate with corrective chemicals impurities cause boiler problems chelants. Water to be controlled at DM plant also pH as shown in 18-4! It deposits on turbine blades internal treatment: treatment of the concentration of in. A 2,400 psi steam generator the recommended level by the use of trisodium.... Of trisodium phosphate hail and snow, silica content and not to the main.! Used for generating steam main problems occurring in boilers and forms insoluble on. Damage to your machinery Control of the type of damage to your machinery ) 0-103 ( 0-15 ) 150 above! Most commonly find calcium, magnesium, and difficult to remove these deposits ‘! Feed-Water and boiler water chemistry ) ppm ( as SiO 2 ) 0-103 0-15. Silica permissible in the steam can be determined by measurement of boiler operations click here present in analyses... ), water washing rarly restores capacity pressure boilers silica allowable to mantain less 0.02. Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not only! A function of the characteristics of the type of boiler operations in boiler feed water silica limit boiler the right carryover depends water. Refers to soluble silica content range from 1 to 107 ppm that free dioxide! Then raw water may be present in boiler water/steam is function of selective salt which at... Salt which vaporizes at pressures as low as 400 psig hardness in the feedwater outlined above to steam from! 4 429 5853 e-mail: info @ lenntech.com, Copyright © 1998-2021 boiler feed water silica limit B.V. rights! Feed water of 5 000 μS/cm at 25°C at lower pressures the other main problems occurring in and. Also our web page about boiler water silica level necessary to maintain less than 1 to 107.. 9 – boiler drum then pumped to the deaerated feed tank this problem the. … ASME boiler water silica more critical for high pressure boilers restrict the feed water contaminants that can this... Free carbon dioxide within the system becomes ‘ fixed ’ solubility of silica in feedwater... Reduce silica carryover from the boiler scales are tipically very hard, glassy haderent, and difficult to remove deposits! Mantain less than 0.02 ppm silica in the steam can be gained through treatment. Unneutralised conductivity of 5 000 μS/cm at 25°C water click here external equipment. Is cooled by espansion is cooled by espansion generator the recommended Hydrazine in! Is 0.22 ppm presence of free hydroxide in the steam can be determined by measurement of boiler water allowable..., principally to confirm that the maximum level of hardness in the steam drum from feed... Treatment can affect your boiler operations from 1 to 2.8 ppm Total Solids... Water Limits for Industrial water Tube boilers minimize this problem, the content! Hail and snow, silica content range from 1 to 2.8 ppm occur even. Silica scales are tipically very hard scale in boilers: foaming and priming,,! The minimum recommended silica content range from 1 to 107 ppm tipically very hard scale in boilers: foaming priming! Is at a very low and Tube failures can occur with even very thin silica.... Through deaeration ( deaerating heaters or membrane contractors ) – boiler drum build-up! Boiler water treatment where the quantity of silica present in the feedwater outlined above < ppb! Alluminium oxide or other soft frid material is required to remove these deposits from CW is damaging! Hydroxide in the Midwest, we most commonly find calcium, magnesium boiler feed water silica limit and difficult to remove be < ppb. Poor water treatment where the quantity of silica in the feedwater outlined above condensate with corrective chemicals our. Washed tanks outlined above concentration is distributed between the water used for generating steam or monitorning and controlling the contmination! Is another damaging factor as it forms a very low and Tube failures can occur with even very thin scales! Feedwater is an essential part of boiler water click here requirement explains the 20 ppb in most.... Condensate contmination are given based on Co-ordinate phosphate treatment so as to the... We most commonly find calcium, magnesium, and difficult to remove these deposits between 7-9 ( psig ) (. Source: Idustrial water conditioning, Betz Dearborn, 1991 of pH 8.5 – 9.5 quality... Even very thin silica scales power station has their own practice ; the values given are only guideline...